I would first look at the media you're using...next would be the ink-limiting in your RIP (perhaps limiting too much?). Best chance at getting the maximum gamut out an inkjet is to use good quality paper that has an L* in the 95-97 range plus the ability to "hold" ink well without mottling.
Out of curiousty, I just measured a solid yellow patch from my HP z2100 on Epson Proofing Paper White Semimatte and I came up with a chroma of around 104....very similar to what you've got. While I love the HP z2100, my Epson printers (9600/7800) can pretty routinely get solid yellow chroma numbers in the 110 range.
It's a fact of life that, despite the "wide" gamut of inkjet printers in general, many of them will have a hard time with the orange/red/magenta region of the GRACoL gamut.
I would start with a change of paper.....I can recommend both Epson Proofing Paper White Semimatte and Epson Standard Proofing Paper (240) as two very good papers at a reasonable price...and they both work fine on the HP z2100. On the HP, you need to make sure that you're using a starter media type that lays down the maximum amount of ink. Use that as the media type when creating your custom media setting. Then you can use your RIP ink channel limiting to dial it back a bit if needed.
Terry
Terence Wyse, WyseConsul
Color Management Consulting, G7 Certified Expert