It is the alkali blue pigment or even perhaps milori blue that is used in process blacks to make a good, dense, jet and BLUE black. Pigment 61 Red Shade is the most likely culprit.
I have actually encountered this in my past travels and it is due to a chemical interation between the alkali blue and usually the fountain solution. There is also a chance it is being caused by another one of the chemical consumables, interacting negatively, that are run on the press.
So the question is, 'how do I eliminate the problem'?
You have 2 choices.
1) Have the inkmaker formulate a black ink with no fugitive pigments like alkali blue or milori. A combination of carbazole violet and phthalo blue r/s does an excellent job to provide blue toning value in a process black. Another added benefit of the combo, is NO CHANCE for any pigment burn out due to the amines in aqueous and ultraviolet coatings. This change will cause an increase in the material cost of the ink. If you as an inkmaker explain it to the lithographer, exactly as I have outlined it, they should have no problem in paying the extra selling price that will be incurred from the material change.
2) You can experiment with changing the other consumables on press. One thing not mentioned was the press wash. Here is an easy experiment a printer can do in their shop to try to determine the chemical culprit.
Print BLACK ONLY on a coated stock with screen values of 10-20-30-.......up to 100% solid. You only need to run about 25 sheets. Let the form dry down completely, I would say at least 5 days, because today's inks are mostly stay open, and do take that amount of time to truly DRY. Now your ready. Take an eye dropper of all your consumables used on press. Using isopropyl alcohol, apply the various liquids and solutions to the print. Look for ANY bleed whatsoever of the ink films. After you have done this, you can narrow down what is causing the blue to stain your rollers. Fountain solution preppared, raw eth, raw sub, press wash, pre press chemicals used in the plate making process are some of the consumables that should be tested on the black prints.
This is a problem that can definitely be uncovered, discovered and remedied. Just listen to me, because I am the...
D Ink Man