Actually, for a 4CP printer, 100/100/100/100 would tell the printer to lay down the most ink; RGB0,0,0 is like 350% coverage, the 4x 100's would be 400% coverage. Your RIP/printer might limit max coverage, so it might scale things back. In my experience, this type of feature is not documented.
Printing RGB 0,0,0 will NOT necessarily give a neutral black. It will if you're using a good rip, though.
That being said, let's talk about substrate. If you're printing on anything paper-y, you'll be best to stick with pure black because you'll get ripples with heavy coverage.
If you're printing on high quality (not paper) inkjet-type media, you could go with one of the standard rich black recipes - 40-40-40-100 or 60-40-40-100 etc.
To the point, if I'm printing on anything resembling uncoated paper, I'm pure black all the way.
If I'm printing on synthetic materials like vinyl or poly I'll use 60-40-40-100 (my fave rich black)
If I'm printing on canvas, I might use 100-100-100-100 because the canvas can handle the extreme coverage.
If I'm printing on something I shouldn't be running through an inkjet (coated paper, non-inkjet media, etc), I'll use pure black so it doesn't smear/offset
Really, it's all in the media.